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Aqueous zinc ion batteries (AZIBs) are considered one of the most promising large-scale energy storage systems due to their high energy density and inherent safety. However, the severe dendrite growth of the zinc anode, the severe degradation of the anode, and the boundedness of the diaphragm limit the application of AZIBs. nanofber machime, with the advantages of controllable nanostructures, high electrical conductivity, and large specific surface area, has a great potential and a broad application prospect for constructing AZIBs with excellent electrochemical properties.
1.This paper firstly briefly introduces the principle and process of electrospinnig machine, as well as the structural design of electrostatically spun fibres in AZIBs.
2.It reviews the research progress of electrostatic spinning nanofibres in AZIBs in recent years, including positive electrode, negative electrode and diaphragm, focusing on the working mechanism of Electrospun Nanofbers and the relationship between electrode structure and performance.
3.Finally, the prospect of the development of high-performance electrospun fibres for AZIBs is envisioned.
1.Preparation of N-doped carbon fibres to improve the electronic conductivity of cathode materials.
2.Preparation of Zn-friendly carbon nanofibre interlayers for uniform Zn^2+ deposition.
3.Preparation of polyacrylonitrile (PAN) Nanofiber Membrane with high porosity and excellent flexibility.
4.Preparation of core/shell structured nanofibre electrode materials.
5.Preparation of Electrospun Nanofbers with porous structure to improve the specific surface area and volume change during cycling.
6.Synthesis of vanadium nitride-embedded nitrogen-doped carbon nanofibres (VN/N-CNFs) composite laminated structures.
7.Application of Electrospun Nanofbers in AZIBs cathode, anode and diaphragm to improve their electrochemical performance.
Electrospun Nanofber is expected to enhance the electronic conductivity of the material, facilitate ion diffusion, and improve the rate performance and cycling ability of AZIBs.
Electrospun Nanofber's porous and flexible nature helps maintain the structural stability of the electrodes, accommodates volume changes, and inhibits the dissolution of active materials.
Electrospun Nanofber can be used as bending electrodes without adhesives, offering prospects for the development of bendable and wearable AZIB devices.
New materials with tailored properties, such as zincophilic and hydrophilic properties, can be developed using Electrospun Nanofber to facilitate the uniform deposition of zinc and improve the performance of AZIBs.
In summary, while there are challenges that need to be addressed, Electrospun Nanofber
Original link: https://doi.org/10.1039/D3SC05283D